
Daqing Oil Field ASP Projects, Daqing, China
Polymer flood was successful in Daqing and its incremental recovery over water flood is more than 12% OOIP. Up to 1998, Daqing produced 8.16 million tons of the crude oil by polymer flooding. Micelle flooding was then field tested and concluded technically successful but not economical. In order to lower the cost of chemical flooding, Alkaline Surfactant Polymer flooding was studied in the laboratory and tested in the field. Both numerical simulation and the pilot results showed more than 20% OOIP over the water flooding. The actual production data was better than the numerical simulation, even in a reservoir with long-term 100% water cut. Daqing Oil Field obtained rather high oil recovery with the low acid number crude oil.
ORS-41 was used in Field No. 4. Laboratory tests showed that adsorption was minimal for this surfactant. The results of four of these tests are shown in Figure 1. Oil recoveries were exceptionally high using 0.3wt% ORS-41, 1.2% NaOH and 1000 mg/L polymer. The study concluded that over 20% OIIP over water flooding oil could be recovered using ASP, chemical cost per ton of incremental oil was calculated to be about US$5/bbl.

Tanner Field ASP Project, Wyoming, USA
The Tanner field is a sandstone formation containing
21° API gravity crude with a viscosity of 11 cp at a
reservoir temperature of 175º F (79º C). The
reservoir is 8915 feet (2717 m) deep with an average
porosity of 20% and an average permeability of 200
mD. The reservoir is 25 ft (7.32 m) thick. The
Tanner field ASP flood is very unique in that
alkaline-surfactant-polymer injection began after a
short water flood when the oil cut was 43%.
The ASP flood used 1.0 wt% NaOH, 0.1 wt% ORS-41 and
800 mg/L Alcoflood 1275A (polyacrylamide polymer).
0.251 pore volume (PV) of ASP solution amounting to
642,000 bbls was injected followed by 0.52 PV or
644,685 bbls of tapered polymer were injected. This
was followed by 0.092 PV or 236,000 bbls of water
through 2005.
The chemical and plant costs were $1,430,000.
Incremental operating cost was negligible since a
water flood would have operated throughout the
chemical injection. Figure 2 shows the results
before and after the introduction of the ASP flood
to the Tanner field. Note the sharp divergence in
the actual oil cut after ASP and the extrapolated
oil cut if ASP were not to have been employed.
The project is projected to produce an additional
17% of the OOIP beyond that producible by water
injection. The total cost of chemicals, plant and
engineering was US$ 5.85 per incremental barrel of
oil recovered. Payout was 2.5 years based on the
cost of oil in the period 2000 - 2005.

Reference: SPE 100004
Sho-Vel-Tum Field ASP Project, Oklahoma, USA
An ASP flood in the Sho-Vel-Tum field sponsored by
the US Department of Energy. This was a small pilot
test to prove the feasibility of the ASP process.
The well is located in Oklahoma, USA and the
reservoir is only 700 feet (214 m) deep making it
the shallowest well in the United States where an
ASP flood has been initiated. The well has been
producing for over 40 years and was producing 4
bbl/day before the ASP project was initiated. The
ASP project increased average oil recovery from 4
bbl/day to 20 bbl/day. The pilot project added
10,444 barrels of incremental oil over a period of
1.3 years.
The ASP system consisted of 0.5 wt% ORS-62 2.20 wt%
Na2CO3 and 1000 mg/l Alcoflood 1275A polymer in
softened water. Project costs were $26,479 for
14,000 lbs polymer, $25,479 for 47,980 lbs ORS-62
and $14,854 for 73.3 tons of sodium bicarbonate. The
cost per incremental barrel oil is estimated to be
about $4/bbl making the project economical even when
the oil price was $18/bbl.
Reference: SPE
84904
Taber South ASP Project, Alberta, Canada
Taber South was producing 300 bbl/day before the ASP
flood. ASP injection started in June 2006.
Production increased to 1,502 bbl/day as of December
2007. Oil cuts increased from 1.7% to 7.3% over the
same period.

Reference: Masters Energy February 2008 Corporate Presentation
Alkali Surfactant Flood Field Published Results
Big Sinking Field AS Flood, Kentucky, USA
Alkali surfactant was implemeted to improve the
injectivity of a waterflood located in the Big
Sinking Field, Kentucky USA. The reservoir contains
100 Million barrels of oil at a depth of 1150 feet
(350 meters) and a bottom hole temperature of 30º C.
The reservoir is 25 feet (7.32 meters) in thickness
and the permeability is 45 mD. The field was
experiencing high water cuts and very low
injectivity. After injecting a solution containing
0.8 wt% sodium hydroxide (NaOH) and 0.1 wt%
ORS-162HF the injectivity was improved 220%. This
solution lowered the interfacial tension (IFT)
between the injection brine and the crude oil in the
reservoir from the original value of 23.6 dyne/cm to
0.001 dyne/cm.
Pilot tests were run in 2003 by first injecting
fresh water to establish an initial injection rate.
This was followed by injection of NaOH and ORS-162HF
alkaline surfactant solution. The fresh water return
after injecting 1,500 barrels (238 m3) increased
from 41 to 75 barrels per day (6.5 to 11.9 m3). The
injectivity was increased by 220%.
The economic analysis of the project showed that a
30 barrel (4.8 m3) increase in injectivity for a
mature waterflood with an efficiency of 15:1
(barrels injected/barrel oil produced) would result
in a payout of approximately 8 months with oil at
US$25/bbl (US$4/m3). At today's oil prices of US
$80-90/bbl this would result in a payout of less
than 3 months.
Reference: SPE
89384
Angsi Field Offshore AS Flood, Malaysia
Alkaline surfactant pilot project was implemented in
Angsi field located offshore Terengganu, Malaysia,
to evaluate the effectiveness of the alkaline
surfactant process in improving oil recovery through
the reduction of residual oil saturation. Oil
Chemical Technologies' SS 6-72LV was one the
surfactant used in the pilot test. The alkali
surfactant solution was injected into Angsi I-68
reservoir as a single well tracer test used to
determine the residual oil saturation. The Angsi is
the second largest reservoir with the expected
recovery factor of 39% of the OOIP. The crude oil
gravity is an average of 42 API. Oil viscosity is
0.3 cps at reservoir temperature of 119 °C.
Reference: SPE
109033
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